Multiplication and division are different beasts than addition and subtraction. To master any new concept, students have to think in a different way in regards to reasoning mathematically. Of course, this requires you to approach division in your homeschool program with a plan to help your daughter understand it. With that in mind, here are some ways to teach the concept:
Go over rules of divisibility
Introducing your daughter to the rules of divisibility may help her begin to understand division. There are rules for dividing by 2, 3, 4, 5, 6, 8, 9 and 10, and they go as follows:
Knowing these rules can help your daughter look at a number and discover what it's divisible by - in some cases, multiple rules will apply to the same number.
Connect to subtraction
Your daughter already knows subtraction and likely multiplication, so use these tools to teach division. For instance, use subtraction in this way:
Express 12/2 as 12 - 2 - 2 - 2 - 2 - 2 - 2 = 6.
This shows how many times 12 can be split in half. You can simplify it as (3 x 2) + (3 x 2) = 12, and then 6 x 2 = 12
The inverse of that is 12/2 = 6.